A fragrant of essential oils and/or aroma compounds, fixatives, scented mixtures, and solvents, has much of its basic ingredients incense based. Perfumery or the art of making perfumes began thousands of years in ancient Mesopotamia and Egypt, and its making was described to us by various pioneers in the field. From Pliny the Elder, as of basic ingredients and methods in his Naturalis Historia, Tapputi a perfume maker mentioned in a Cuneiform tablet in the 2nd millennium BC in Mesopotamia, the earliest distillation of Attar in India with a 7th century document mentioning the use of fragrant agar wood in the making, the 4000year old factory in Pyrgos in Cyprus, the Egyptian’s use of exotic materials, such as ebony and porcelain, putting it in attractive glass bottles, the more precious than jewels then, and selling it the way it is sold today, to the Greeks whose passion to lilies and roses made them create the first liquid perfumes, of  fragrant powders mixed with heavy oils devoid of alcohol, and eventually  to the Romans who went on refining it, increasing its variety, putting it in all kinds of jars and pots of all shapes and sizes, and releasing it as they and their pets went, spreading it on furniture and in everyplace around creating a rich fragrant society.     
Thanks to the Arabs who further refined the making, a process highly attributed to the Arab Chemists Jaber Ibn Hayyan who developed many techniques of distillation, evaporation and filtration, and Al Kindi who established the perfume industry, through a book on perfumes describing tens of recipes and methods for perfume making and perfume making equipment. The Persians had their part in the making through Ibn Sina or Avicenna who introduced the process of extracting oils from flowers by means of distillation the method commonly used today. These participations were the laden foundations for the development of Western perfumery in perfecting the extraction of fragrances through steam distillation and new raw ingredients and in the advancement of sciences especially Chemistry.
The Westerners had their contributions; the Italians seemed to have started perfume making ever since 1221 in Florence Italy, while the Hungary water, a perfume made of scented oils blended in an alcohol solution was the specialty of the Hungarians. The art of perfumery witnessed an elevation during the Renaissance with the Italian refinements taken to France, making it quickly the European center for perfume and cosmetic manufacture. With Louis XV demanding a different fragrance every day, the British ladies took pride in creating delightful fragrances with varying mixing scents. The Italians made Germany the birth of eau de cologne and the Americans started the Florida water. This molding of eau de cologne with various flowers, oils and scented waters, coupled with changing tastes and the development of modern chemistry laid the foundations of perfumery as we know it today.
Perfumery, or the art of making perfumes, began in ancient Egypt but was developed and further refined by the Romans and the Arabs. Although perfume and perfumery also existed in East Asia, much of its fragrances are incense based. The basic ingredients and methods of making perfumes are described by Pliny the Elder in his Naturalis Historia.
Mesopotamia
The world's first recorded chemist is a person named Tapputi, a perfume maker who was mentioned in a Cuneiform tablet from the 2nd millennium BC in Mesopotamia. Perfume is thoughtands years old and is made from fragrance
India
Perfume and perfumery also existed in India, much of its fragrances were incense based. The earliest distillation of Attar was mentioned in the Hindu Ayurvedic text Charaka Samhita. The Harshacharita, written in 7th century A.D. in Northern India mentions use of fragrant agar wood oil.[citation needed]
Cyprus
To date, the oldest perfumery was discovered on the island of Cyprus. Excavations in 2004-5 under the initiative of an Italian archaeological team unearthed evidence of an enormous factory that existed 4,000 years ago during the Bronze Age. This covered an estimated surface area of over 4,000m² indicating that perfume manufacturing was on an industrial scale. The news of this discovery was reported extensively through the world press and many artifacts are already on display in Rome. The Bible describes a sacred perfume (Exodus 30:22-33) consisting of liquid myrrh, fragrant cinnamon, fragrant cane, and cassia. Its use was forbidden, except by the priests. The woman wore perfume to present their beauty.
Islamic
Islamic cultures contributed significantly in the development of Western perfumery in both perfecting the extraction of fragrances through steam distillation and introducing new, raw ingredients. Both of the raw ingredients and distillation technology significantly influenced Western perfumery and scientific developments, particularly chemistry.
As traders, Islamic cultures such as the Arabs and Persians had wider access to different spices, herbals, and other fragrance material. In addition to trading them, many of these exotic materials were cultivated by the Muslims such that they can be successfully grown outside of their native climates. Two examples of this include jasmine, which is native to South and Southeast Asia, and various citrus, which are native to East Asia. Both of these ingredients are still highly important in modern perfumery.
In Islamic culture, perfume usage has been documented as far back as the 6th century and its usage is considered a religious duty. Muhammad said:
“The taking of a bath on Friday is compulsory for every male Muslim who has attained the age of puberty and (also) the cleaning of his teeth with Miswaak (type of twig used as a toothbrush), and the using of perfume if it is available. (Recorded in Sahih Bukhari)”
Such rituals gave incentives to scholars to search and develop a cheaper way to produce incenses and in mass production. Thanks to the hard work of two talented Arabian chemists: Jābir ibn Hayyān (Geber, born 722, Iraq), and Al-Kindi (Alkindus, born 801, Iraq) who established the perfume industry. Jabir developed many techniques, including distillation, evaporation and filtration, which enabled the collection of the odour of plants into a vapour that could be collected in the form of water or oil.
Al-Kindi, however, was the real founder of perfume industry as he carried out extensive research and experiments in combining various plants and other sources to produce a variety of scent products. He elaborated a vast number of ‘recipes’ for a wide range of perfumes, cosmetics and pharmaceuticals. His work in the laboratory is reported by a witness who said:
“I received the following description, or recipe, from Abu Yusuf Ya'qub b. Ishaq al-Kindi, and I saw him making it and giving it an addition in my presence.”
The writer goes on in the same section to speak of the preparation of a perfume called ghaliya, which contained musk, amber and other ingredients; too long to quote here, but which reveals a long list of technical names of drugs and apparatus. Al-Kindi also wrote in the 9th century a book on perfumes which he named ‘Book of the Chemistry of Perfume and Distillations’. It contained more than hundred recipes for fragrant oils, salves, aromatic waters and substitutes or imitations of costly drugs. The book also described one hundred and seven methods and recipes for perfume-making, and even the perfume making equipment, like the alembic, still bears its Arabic name.
The Persian Muslim doctor and chemist Avicenna (also known as Ibn Sina) introduced the process of extracting oils from flowers by means of distillation, the procedure most commonly used today. He first experimented with the rose. Until his discovery, liquid perfumes were mixtures of oil and crushed herbs, or petals which made a strong blend. Rose water was more delicate, and immediately became popular. Both of the raw ingredients and distillation technology significantly influenced western perfumery and scientific developments, particularly chemistry.
Eggs and floral perfumes were brought to Europe in the 11th and 12th centuries from Arabia, through trade with the Islamic world and with the returning Crusaders. Those who traded for these were most often also involved in trade for spices and dyestuffs. There are records of the Pepperers Guild of London, going back to 1179; which show them trading with Muslims in spices, perfume ingredients and dyes.
Western
Knowledge of something perfumery came to Europe as early as the 14th century due partially to Arabic influences and knowledge. But it was the Hungarians who ultimately introduced the first modern perfume. The first modern perfume, made of scented oils blended in an alcohol solution, was made in 1370 at the command of Queen Elizabeth of Hungary and was known throughout Europe as Hungary Water. The art of perfumery prospered in Renaissance Italy, and in the 16th century, Italian refinements were taken to France by Catherine de' Medici's personal perfumer, Rene le Florentin. His laboratory was connected with her apartments by a secret passageway, so that no formulas could be stolen en route.
France quickly became the European center of perfume and cosmetic manufacture. Cultivation of flowers for their perfume essence, which had begun in the 14th century, grew into a major industry in the south of France. During the Renaissance period, perfumes were used primarily by royalty and the wealthy to mask body odors resulting from the sanitary practices of the day. Partly due to this patronage, the western perfumery industry was created. Perfume enjoyed huge success during the 17th century. Perfumed gloves became popular in France and in 1656, the guild of glove and perfume-makers was established. Perfumers were also known to create poisons; for instance, a French duchess was murdered when a perfume/poison was rubbed into her gloves and was slowly absorbed into her skin.
Perfume came into its own when Louis XV came to the throne in the 18th century. His court was called "le cour parfumee" (the perfumed court). Madame de Pompadour ordered generous supplies of perfume, and King Louis demanded a different fragrance for his apartment every day. The court of Louis XIV was even named due to the scents which were applied daily not only to the skin but also to clothing, fans and furniture. Perfume substituted for soap and water. The use of perfume in France grew steadily. By the 18th century, aromatic plants were being grown in the Grasse region of France to provide the growing perfume industry with raw materials. Even today, France remains the centre of the European perfume design and trade. After Napoleon came to power, exorbitant expenditures for perfume continued. Two quarts of violet cologne were delivered to him each week, and he is said to have used sixty bottles of double extract of jasmine every month. Josephine had stronger perfume preferences. She was partial to musk, and she used so much that sixty years after her death the scent still lingered in her boudoir.
England
Perfume reached its peak in England during the reigns of Henry VIII and Queen Elizabeth I. All public places were scented during Queen Elizabeth's rule, since she could not tolerate bad smells. It was said that the sharpness of her nose was equaled only by the slyness of her tongue. Ladies of the day took great pride in creating delightful fragrances and they displayed their skill in mixing scents.
As with industry and the arts, perfume was to undergo profound change in the 19th century. Changing tastes and the development of modern chemistry laid the foundations of perfumery as we know it today. Alchemy gave way to chemistry and new fragrances were created. The industrial revolution had in no way diminished the taste for perfume, there was even a fragrance called "Parfum à la Guillotine". Under the post-revolutionary government, people once again dared to express a penchant for luxury goods, including perfume. A profusion of vanity boxes containing perfumes appeared in the 19th century.
Americas
In early America, the first scents were colognes and scented water. Florida water, an uncomplicated mixture of eau de cologne with a dash of oil of cloves, cassia, and lemongrass, was popular.
Article source : http://en.wikipedia.org/wiki/History_of_perfume

Due to its jasmine, rose and orange-growing trades, the town of Grasse in Provence established itself as the largest production center for raw materials. The statutes of the perfume-makers of Grasse were passed in 1724. Paris became the commercial counterpart to Grasse and the world center of perfume. Perfume houses such as Houbigant (Quelques Fleurs, still very popular today), Lubin, Roger & Gallet, and Guerlain were all based in Paris. In 1760, in London, James Henry Creed founded the House of Creed perfume.
With the turn of the century fragrance houses emerged in Europe. The Crown Perfumery was founded in 1872 by William Sparks Thomson, a maker of crinolines and corsets. Catering to the high society in London and Europe, he launched a collection of floral fragrances called Flower Fairies. Queen Victoria granted the Crown Perfumery her own crown's image to top the fragrance bottles. In 2002 Clive Christian discontinued the Crown line of fragrances and replaced them with the luxurious Clive Christian perfume line.
Soon bottling became more important. Perfume maker Francois Coty formed a partnership with Rene Lalique. Lalique then produced bottles for Guerlain perfume, D'Orsay, Lubin, Molinard, Roger & Gallet and others. Baccarat then joined in, producing the bottle for Mitsouko (Guerlain), Shalimar (Guerlain) and others. Brosse glassworks created the memorable bottle for Jeanne Lanvin's Arpege perfume, the famous Chanel No.5, and most recently for Parfums Raffy single note fragrances. Floral fragrances became more popular in the 20th century. Fracas perfume by Robert Piguet fragrances was first released in 1948 by master perfumer Germaine Cellier and is known as the premier Tuberose fragrance.
In 1921- Couturier Gabrielle Chanel launched her own brand of perfume, created by Ernest Beaux, she calls it Chanel No.5 because it was the fifth in a line of fragrances Ernest Beaux presented her. Ernest Beaux was the first perfumer to use aldehydes regularly in perfumery.
The 1930's saw the arrival of the leather fragrances, and florals, also became quite popular with the emergence of Worth's Je Reviens (1932), Caron's Fleurs de Rocaille (1933) and Jean Patou's Joy perfume (1935). With French perfumery at it's peak in the 1950's, other designers such as Christian Dior, Jacques Fath, Nina Ricci perfume, Pierre Balmain and so on, started creating their own scents.
The recent popularity of celebrity fragrances has also made an impact on the industry although most experts do not expect the trend to last. Today there are over 30,000 designer perfumes on the market and perfumes are no longer for the wealthy. The perfume industry has undergone several changes in technique, material and style. All of which have created the modern fragrance industry, one that still incorporates creativity,  mystique and romance along with marketing to appeal to the masses.
In recent years the emergence of small and exclusive fragrance brands have been marketed. Known as niche fragrances, brands such as Amouage, Montale perfume, Xerjoff, Parfumerie Naturelle, Bois 1920, Odori perfume are bringing back the high quality fine fragrances of the past perfume artisans. These fragrances contain the finest oils from all over the world and have revived the passion of perfumery for so many. Perfume samples are a great way to try these niche fragrances.
Article source : http://www.parfumsraffy.com/history.html
- Chapter III: Types and Concentration of Perfume
Concentration
Perfume types reflect the concentration of aromatic compounds in a solvent, which in fine fragrance is typically ethanol or a mix of water and ethanol. Various sources differ considerably in the definitions of perfume types. The intensity and longevity of a perfume is based on the concentration, intensity and longevity of the aromatic compounds (natural essential oils / perfume oils) used: As the percentage of aromatic compounds increases, so does the intensity and longevity of the scent created. Specific terms are used to describe a fragrance's approximate concentration by percent/volume of perfume oil, which are typically vague or imprecise. A list of common terms (Perfume-Classification) is as follows:
Perfume extract, or simply perfume (Extrait): 15-40% (IFRA: typical 20%) aromatic compounds
Esprit de Parfum (ESdP): 15-30% aromatic compounds, a seldom used strength concentration in between EdP and perfume
Eau de Parfum (EdP), Parfum de Toilette (PdT): 10-20% (typical ~15%) aromatic compounds, sometimes listed as "eau de perfume" or "millésime"
Eau de toilette (EdT): 5-15% (typical ~10%) aromatic compounds
Eau de Cologne (EdC): Chypre citrus type perfumes with 3-8% (typical ~5%) aromatic compounds. "Original Eau de Cologne" is a registered trademark.
Perfume mist: 3-8% aromatic compounds (typical non-alcohol solvent)
Splash (EdS) and After shave: 1-3% aromatic compounds. "EdS" is a registered trademark.
Solvent types
Perfume oils are often diluted with a solvent, though this is not always the case, and its necessity is disputed. By far the most common solvent for perfume oil dilution is ethanol or a mixture of ethanol and water. Perfume oil can also be diluted by means of neutral-smelling oils such as fractionated coconut oil, or liquid waxes such as jojoba oil.
Imprecise terminology
Although quite often, Eau de Parfum (EdP) will be more concentrated than Eau de Toilette (EdT) and in turn Eau de Cologne (EdC), this not always the case. Different perfumeries or perfume houses assign different amounts of oils to each of their perfumes. Therefore, although the oil concentration of a perfume in EdP dilution will necessarily be higher than the same perfume in EdT from within the same range, the actual amounts can vary between perfume houses. An EdT from one house may be stronger than an EdP from another.
Men's fragrances are rarely sold as EdP or perfume extracts; equally so, women's fragrances are rarely sold in EdC concentrations. Although this gender specific naming trend is common for assigning fragrance concentrations, it does not directly have anything to do with whether a fragrance was intended for men or women. Furthermore, some fragrances with the same product name but having a different concentration name may not only differ in their dilutions, but actually use different perfume oil mixtures altogether. For instance, in order to make the EdT version of a fragrance brighter and fresher than its EdP, the EdT oil may be "tweaked" to contain slightly more top notes or fewer base notes. In some cases, words such as extrême, intense, or concentrée that might indicate aromatic concentration are actually completely different fragrances, related only because of a similar perfume accord. An example of this is Chanel's Pour Monsieur and Pour Monsieur Concentrée.
Eau de Cologne (EdC) since 1706 in Cologne, Germany, is originally a specific fragrance and trademark. However outside of Germany the term has become generic for Chypre citrus perfumes (without base-notes). EdS (since 1993) is a new perfume class and a registered trademark.
Describing a perfume
The precise formulae of commercial perfumes are kept secret. Even if they were widely published, they would be dominated by such complex ingredients and odorants that they would be of little use in providing a guide to the general consumer in description of the experience of a scent. Nonetheless, connoisseurs of perfume can become extremely skillful at identifying components and origins of scents in the same manner as wine experts.
The most practical way to start describing a perfume is according to the elements of the fragrance notes of the scent or the "family" it belongs to, all of which affect the overall impression of a perfume from first application to the last lingering hint of scent.
Fragrance notes
Main article: Note (perfumery)
Perfume is described in a musical metaphor as having three sets of notes, making the harmonious scent accord. The notes unfold over time, with the immediate impression of the top note leading to the deeper middle notes, and the base notes gradually appearing as the final stage. These notes are created carefully with knowledge of the evaporation process of the perfume.
Top notes: The scents that are perceived immediately on application of a perfume. Top notes consist of small, light molecules that evaporate quickly. They form a person's initial impression of a perfume and thus are very important in the selling of a perfume. Also called the head notes.
Middle notes: The scent of a perfume that emerges just prior to when the top notes dissipate. The middle note compounds form the "heart" or main body of a perfume and act to mask the often unpleasant initial impression of base notes, which become more pleasant with time. They are also called the heart notes.
Base notes: The scent of a perfume that appears close to the departure of the middle notes. The base and middle notes together are the main theme of a perfume. Base notes bring depth and solidity to a perfume. Compounds of this class of scents are typically rich and "deep" and are usually not perceived until 30 minutes after application.
The scents in the top and middle notes are influenced by the base notes, as well the scents of the base notes will be altered by the type of fragrance materials used as middle notes. Manufacturers of perfumes usually publish perfume notes and typically they present it as fragrance pyramid, with the components listed in imaginative and abstract terms.
Olfactive families
Grouping perfumes, like any taxonomy, can never be a completely objective or final process. Many fragrances contain aspects of different families. Even a perfume designated as "single flower", however subtle, will have undertones of other aromatics. "True" unitary scents can rarely be found in perfumes as it requires the perfume to exist only as a singular aromatic material.
Classification by olfactive family is a starting point for a description of a perfume, but it cannot by itself denote the specific characteristic of that perfume.
Traditional
The traditional classification which emerged around 1900 comprised the following categories:
Single Floral: Fragrances that are dominated by a scent from one particular flower; in French called a soliflore. (e.g. Serge Lutens' Sa Majeste La Rose, which is dominated by rose.)
Floral Bouquet: Is a combination of fragrance of several flowers in a perfume compound. Examples include Quelques Fleurs by Houbigant and Joy by Jean Patou.
Ambered, or "Oriental": A large fragrance class featuring the sweet slightly animalic scents of ambergris or labdanum, often combined with vanilla, tonka bean, flowers and woods. Can be enhanced by camphorous oils and incense resins, which bring to mind Victorian era imagery of the Middle East and Far East. Traditional examples include Guerlain's Shalimar and Yves Saint Laurent's Opium.
Wood: Fragrances that are dominated by woody scents, typically of agarwood, sandalwood and cedarwood. Patchouli, with its camphoraceous smell, is commonly found in these perfumes. A traditional example here would be Myrurgia's Maderas De Oriente or Chanel Bois-des-Îles. A modern example would be Balenciaga Rumba.
Leather: A family of fragrances which features the scents of honey, tobacco, wood and wood tars in its middle or base notes and a scent that alludes to leather. Traditional examples include Robert Piguet's Bandit and Balmain's Jolie Madame.
Chypre (IPA: [ʃipʁ]): Meaning Cyprus in French, this includes fragrances built on a similar accord consisting of bergamot, oakmoss, patchouli, and labdanum. This family of fragrances is named after a perfume by François Coty, and one of the most famous examples is Guerlain's Mitsouko.
Fougère (IPA: [fu.ʒɛʁ]): Meaning Fern in French, built on a base of lavender, coumarin and oakmoss. Houbigant's Fougère Royale pioneered the use of this base. Many men's fragrances belong to this family of fragrances, which is characterized by its sharp herbaceous and woody scent. Some well-known modern fougères are Fabergé Brut and Guy Laroche Drakkar Noir.
Modern
Since 1945, due to great advances in the technology of perfume creation (i.e., compound design and synthesis) as well as the natural development of styles and tastes; new categories have emerged to describe modern scents:
Bright Floral: combining the traditional Single Floral & Floral Bouquet categories. A good example would be Estée Lauder's Beautiful.
Green: a lighter and more modern interpretation of the Chypre type, with pronounced cut grass, crushed green leaf and cucumber-like scents. Two examples would be Estée Lauder's Aliage or Sisley's Eau de Campagne.
Aquatic, Oceanic, or Ozonic: the newest category in perfume history, appearing in 1991 with Christian Dior's Dune. A very clean, modern smell leading to many of the modern androgynous perfumes. Generally contains calone, a synthetic scent discovered in 1966. Also used to accent floral, oriental, and woody fragrances.
Citrus: An old fragrance family that until recently consisted mainly of "freshening" eau de colognes, due to the low tenacity of citrus scents. Development of newer fragrance compounds has allowed for the creation of primarily citrus fragrances. A good example here would be Brut.
Fruity: featuring the aromas of fruits other than citrus, such as peach, cassis (black currant), mango, passion fruit, and others. A modern example here would be Ginestet Botrytis.
Gourmand (IPA: [guʁmɑ̃]): scents with "edible" or "dessert"-like qualities. These often contain notes like vanilla, tonka bean and coumarin, as well as synthetic components designed to resemble food flavors. A sweet example is Thierry Mugler's Angel. A savory example would be Dinner by BoBo, which has cumin and curry hints.
Fragrance wheel
Main article: Fragrance wheel
The Fragrance wheel is a relatively new classification method that is widely used in retail and in the fragrance industry. The method was created in 1983 by Michael Edwards, a consultant in the perfume industry, who designed his own scheme of fragrance classification. The new scheme was created in order to simplify fragrance classification and naming scheme, as well as to show the relationships between each of the individual classes.
The five standard families consist of Floral, Oriental, Woody, Fougère, and Fresh, with the former four families being more "classic" while the latter consisting of newer bright and clean smelling citrus and oceanic fragrances that have arrived due to improvements in fragrance technology. Each of the families are in turn divided into sub-groups and arranged around a wheel.
Aromatics sources
Plant sources
Plants have long been used in perfumery as a source of essential oils and aroma compounds. These aromatics are usually secondary metabolites produced by plants as protection against herbivores, infections, as well as to attract pollinators. Plants are by far the largest source of fragrant compounds used in perfumery. The sources of these compounds may be derived from various parts of a plant. A plant can offer more than one source of aromatics, for instance the aerial portions and seeds of coriander have remarkably different odors from each other. Orange leaves, blossoms, and fruit zest are the respective sources of petitgrain, neroli, and orange oils.
Bark: Commonly used barks includes cinnamon and cascarilla. The fragrant oil in sassafras root bark is also used either directly or purified for its main constituent, safrole, which is used in the synthesis of other fragrant compounds.
Flowers and blossoms: Undoubtedly the largest and most common source of perfume aromatics. Includes the flowers of several species of rose and jasmine, as well as osmanthus, plumeria, mimosa, tuberose, narcissus, scented geranium, cassie, ambrette as well as the blossoms of citrus and ylang-ylang trees. Although not traditionally thought of as a flower, the unopened flower buds of the clove are also commonly used. Most orchid flowers are not commercially used to produce essential oils or absolutes, except in the case of vanilla, an orchid, which must be pollinated first and made into seed pods before use in perfumery.
Fruits: Fresh fruits such as apples, strawberries, cherries unfortunately do not yield the expected odors when extracted; if such fragrance notes are found in a perfume, they are synthetic. Notable exceptions include litsea cubeba, vanilla, and juniper berry. The most commonly used fruits yield their aromatics from the rind; they include citrus such as oranges, lemons, and limes. Although grapefruit rind is still used for aromatics, more and more commercially used grapefruit aromatics are artificially synthesized since the natural aromatic contains sulfur and its degradation product is quite unpleasant in smell.
Leaves and twigs: Commonly used for perfumery are lavender leaf, patchouli, sage, violets, rosemary, and citrus leaves. Sometimes leaves are valued for the "green" smell they bring to perfumes, examples of this include hay and tomato leaf.
Resins: Valued since antiquity, resins have been widely used in incense and perfumery. Highly fragrant and antiseptic resins and resin-containing perfumes have been used by many cultures as medicines for a large variety of ailments. Commonly used resins in perfumery include labdanum, frankincense/olibanum, myrrh, Peru balsam, gum benzoin. Pine and fir resins are a particularly valued source of terpenes used in the organic synthesis of many other synthetic or naturally occurring aromatic compounds. Some of what is called amber and copal in perfumery today is the resinous secretion of fossil conifers.
Roots, rhizomes and bulbs: Commonly used terrestrial portions in perfumery include iris rhizomes, vetiver roots, various rhizomes of the ginger family.
Seeds: Commonly used seeds include tonka bean, carrot seed, coriander, caraway, cocoa, nutmeg, mace, cardamom, and anise.
Woods: Highly important in providing the base notes to a perfume, wood oils and distillates are indispensable in perfumery. Commonly used woods include sandalwood, rosewood, agarwood, birch, cedar, juniper, and pine. These are used in the form of macerations or dry-distilled (rectified) forms.
Animal sources
Ambergris: Lumps of oxidized fatty compounds, whose precursors were secreted and expelled by the sperm whale. Ambergris should not be confused with yellow amber, which is used in jewelry. Because the harvesting of ambergris involves no harm to its animal source, it remains one of the few animalic fragrancing agents around which little controversy now exists.
Castoreum: Obtained from the odorous sacs of the North American beaver.
Civet: Also called Civet Musk, this is obtained from the odorous sacs of the civets, animals in the family Viverridae, related to the mongoose. The World Society for the Protection of Animals investigated African civets caught for this purpose.[12]
Hyraceum: Commonly known as "Africa Stone", is the petrified excrement of the Rock Hyrax.[13]
Honeycomb: From the honeycomb of the honeybee. Both beeswax and honey can be solvent extracted to produce an absolute. Beeswax is extracted with ethanol and the ethanol evaporated to produce beeswax absolute.
Deer musk: Originally derived from the musk sacs from the Asian musk deer, it has now been replaced by the use of synthetic musks sometimes known as "white musk".
Other natural sources
Lichens: Commonly used lichens include oakmoss and treemoss thalli.
"Seaweed": Distillates are sometimes used as essential oil in perfumes. An example of a commonly used seaweed is Fucus vesiculosus, which is commonly referred to as bladder wrack. Natural seaweed fragrances are rarely used due to their higher cost and lower potency than synthetics.
Synthetic sources
Main article: Aroma compound
Many modern perfumes contain synthesized odorants. Synthetics can provide fragrances which are not found in nature. For instance, Calone, a compound of synthetic origin, imparts a fresh ozonous metallic marine scent that is widely used in contemporary perfumes. Synthetic aromatics are often used as an alternate source of compounds that are not easily obtained from natural sources. For example, linalool and coumarin are both naturally occurring compounds that can be inexpensively synthesized from terpenes. Orchid scents (typically salicylates) are usually not obtained directly from the plant itself but are instead synthetically created to match the fragrant compounds found in various orchids.
One of the most commonly used class of synthetic aromatic by far are the white musks. These materials are found in all forms of commercial perfumes as a neutral background to the middle notes. These musks are added in large quantities to laundry detergents in order to give washed clothes a lasting "clean" scent.
The majority of the world's synthetic aromatics are created by relatively few companies. They include:
International Flavors and Fragrances (IFF)
Givaudan
Firmenich
Takasago
Symrise
Each of these companies patents several processes for the production of aromatic synthetics annually.
Characteristics
Natural and synthetics are used for their different odor characteristics in perfumery

Naturals
Synthetics
Variance
Vary by the times and locations where they are harvested as well as how the product was extracted from the raw material. It's much more difficult to produce consistent products with equivalent odor over years of harvest and production. As such, the perfumer has to "manually" balance-out the natural variations of the ingredients in order to maintain the quality of the perfume. In addition, unscrupulous suppliers may adulterate the actual raw materials by changing its source (adding Indian Jasmine into Grasse Jasmine) or the contents (adding linalool to Rosewood) to increase their profit margin.
Much more consistent than natural aromatics. However, differences in organic synthesis may result in minute differences in concentration of impurities. If these impurities have low smell (detection) thresholds, the differences in the scent of the synthetic aromatic will be significant.
Components
Thousands of chemical compounds; large potential for allergies.
Depending on purity, consists primarily of one chemical compound. Sometimes chiral mixtures of isomers, such as in the case of Iso E Super.[
Scent Uniqueness
Bears a slight resemblance scent to its originating material, depending on the how the extraction method denatures the odoriferous compounds.
Similar to natural scents if the compounds are the same. Novel scent compounds not found in nature will often be unique in their scent and dissimilar to the scents of any naturals.
Price
Perfume composed of largely natural materials are usually much more expensive. Prices are determined by the labor and difficulty of properly extracting each unit of the natural materials as well as its quality.
Perfumes using largely synthetic aromatics can be available at widely-affordable prices. Synthetic aromatics are not necessarily cheaper than naturals, with some synthetics being more costly than most natural ingredients due to various factors such as the complexity of synthesis or extraction procedure. However, due to their low odor threshold, one does not need to use much of these materials to produce a perfume.
Obtaining natural odorants
Main article: Extraction (fragrance)
Before perfumes can be composed, the odorants used in various perfume compositions must first be obtained. Synthetic odorants are produced through organic synthesis and purified. Odorants from natural sources require the use of various methods to extract the aromatics from the raw materials. The results of the extraction are either essential oils, absolutes, concretes, or butters, depending on the amount of waxes in the extracted product.
All these techniques will, to a certain extent, distort the odor of the aromatic compounds obtained from the raw materials. This is due to the use of heat, harsh solvents, or through exposure to oxygen in the extraction process which will denature the aromatic compounds, which either change their odor character or renders them odorless.
Maceration/Solvent extraction: The most used and economically important technique for extracting aromatics in the modern perfume industry. Raw materials are submerged in a solvent that can dissolve the desired aromatic compounds. Maceration lasts anywhere from hours to months. Fragrant compounds for woody and fibrous plant materials are often obtained in this manner as are all aromatics from animal sources. The technique can also be used to extract odorants that are too volatile for distillation or easily denatured by heat. Commonly used solvents for maceration/solvent extraction include hexane, and dimethyl ether. The product of this process is called a "concrete".
Supercritical fluid extraction: A relatively new technique for extracting fragrant compounds from a raw material, which often employs Supercritical CO2. Due to the low heat of process and the relatively nonreactive solvent used in the extraction, the fragrant compounds derived often closely resemble the original odor of the raw material.
Ethanol extraction: A type of solvent extraction used to extract fragrant compounds directly from dry raw materials, as well as the impure oily compounds materials resulting from solvent extraction or enfleurage. Ethanol extraction is not used to extract fragrance from fresh plant materials since these contain large quantities of water, which will also be extracted into the ethanol.
Distillation: A common technique for obtaining aromatic compounds from plants, such as orange blossoms and roses. The raw material is heated and the fragrant compounds are re-collected through condensation of the distilled vapour.
Steam distillation: Steam from boiling water is passed through the raw material, which drives out their volatile fragrant compounds. The condensate from distillation are settled in a Florentine flask. This allows for the easy separation of the fragrant oils from the water. The water collected from the condensate, which retains some of the fragrant compounds and oils from the raw material is called hydrosol and sometimes sold. This is most commonly used for fresh plant materials such as flowers, leaves, and stems.
Dry/destructive distillation: The raw materials are directly heated in a still without a carrier solvent such as water. Fragrant compounds that are released from the raw material by the high heat often undergo anhydrous pyrolysis, which results in the formation of different fragrant compounds, and thus different fragrant notes. This method is used to obtain fragrant compounds from fossil amber and fragrant woods where an intentional "burned" or "toasted" odor is desired.
Fractionation: Through the use of a fractionation column, different fractions distilled from a material can be selectively excluded to modify the scent of the final product. Although the product is more expensive, this is sometimes performed to remove unpleasant or undesirable scents of a material and affords the perfumer more control over their composition process.
Expression: Raw material is squeezed or compressed and the oils are collected. Of all raw materials, only the fragrant oils from the peels of fruits in the citrus family are extracted in this manner since the oil is present in large enough quantities as to make this extraction method economically feasible.
Enfleurage: Absorption of aroma materials into solid fat or wax and then extracting the odorous oil with ethyl alcohol. Extraction by enfleurage was commonly used when distillation was not possible because some fragrant compounds denature through high heat. This technique is not commonly used in the present day industry due to its prohibitive cost and the existence of more efficient and effective extraction methods.
Fragrant extracts
Although fragrant extracts are known to the general public as the generic term "essential oils", a more specific language is used in the fragrance industry to describe the source, purity, and technique used to obtain a particular fragrant extract.
Of these extracts, only absolutes, essential oils, and tinctures are directly used to formulate perfumes.
Absolute: Fragrant materials that are purified from a pommade or concrete by soaking them in ethanol. By using a slightly hydrophilic compound such as ethanol, most of the fragrant compounds from the waxy source materials can be extracted without dissolving any of the fragrantless waxy molecules. Absolutes are usually found in the form of an oily liquid.
Concrete: Fragrant materials that have been extracted from raw materials through solvent extraction using volatile hydrocarbons. Concretes usually contain a large amount of wax due to the ease in which the solvents dissolve various hydrophobic compounds. As such concretes are usually further purified through distillation or ethanol based solvent extraction. Concretes are typically either waxy or resinous solids or thick oily liquids.
Essential oil: Fragrant materials that have been extracted from a source material directly through distillation or expression and obtained in the form of an oily liquid. Oils extracted through expression are sometimes called expression oils.
Pomade: A fragrant mass of solid fat created from the enfleurage process, in which odorous compounds in raw materials are adsorbed into animal fats. Pommades are found in the form of an oily and sticky solid.
Tincture: Fragrant materials produced by directly soaking and infusing raw materials in ethanol. Tinctures are typically thin liquids.
Products from different extraction methods are known under different names even though their starting materials are the same. For instance, orange blossoms from Citrus aurantium that have undergone solvent extraction produces "orange blossom absolute" but that which have been steam distilled is known as "neroli oil".
Composing perfumes
Perfume compositions are an important part of many industries ranging from the luxury goods sectors, food services industries, to manufacturers of various household chemicals. The purpose of using perfume or fragrance compositions in these industries is to affect customers through their sense of smell and entice them into purchasing the perfume or perfumed product. As such there is significant interest in producing a perfume formulation that people will find aesthetically pleasing.
The perfumer
Main article: Perfumer
The job of composing perfumes that will be sold is left up to an expert on perfume composition or known in the fragrance industry as the perfumer. They are also sometimes referred to affectionately as a "Nez" (French for nose) due to their fine sense of smell and skill in smell composition.
The composition of a perfume typically begins with a brief by the perfumer's employer or an outside customer. The customers to the perfumer or their employers, are typically fashion houses or large corporations of various industries. The perfumer will then go through the process of blending multiple perfume mixtures and sell the formulation to the customer, often with modifications of the composition of the perfume.
The perfume composition will then be either used to enhance another product as a functional fragrance (shampoos, make-up, detergents, car interiors, etc.), or marketed and sold directly to the public as a fine fragrance.
Technique
Paper blotters (fr:mouillettes) are commonly used by perfumers to sample and smell perfumes and odorants.
Although there is no single "correct" technique for the formulation of a perfume, there are general guidelines as to how a perfume can be constructed from a concept. Although many ingredients do not contribute to the smell of a perfume, many perfumes include colorants and anti-oxidants to improve the marketability and shelf life of the perfume, respectively.
Basic framework
Perfume oils usually contain tens to hundreds of ingredients and these are typically organized in a perfume for the specific role they will play. These ingredients can be roughly grouped into four groups:
Primary scents (Heart): Can consist of one or a few main ingredients for a certain concept, such as "rose". Alternatively, multiple ingredients can be used together to create an "abstract" primary scent that does not bear a resemblance to a natural ingredient. For instance, jasmine and rose scents are commonly blends for abstract floral fragrances. Cola flavourant is a good example of an abstract primary scent.
Modifiers: These ingredients alter the primary scent to give the perfume a certain desired character: for instance, fruit esters may be included in a floral primary to create a fruity floral; calone and citrus scents can be added to create a "fresher" floral. The cherry scent in cherry cola can be considered a modifier.
Blenders: A large group of ingredients that smooth out the transitions of a perfume between different "layers" or bases. These themselves can be used as a major component of the primary scent. Common blending ingredients include linalool and hydroxycitronellal.
Fixatives: Used to support the primary scent by bolstering it. Many resins, wood scents, and amber bases are used as fixatives.
The top, middle, and base notes of a fragrance may have separate primary scents and supporting ingredients. The perfume's fragrance oils are then blended with ethyl alcohol and water, aged in tanks for several weeks and filtered through processing equipment to, respectively allow the perfume ingredients in the mixture to stabilize and to remove any sediment and particles before the solution can be filled into the perfume bottles.
Fragrance bases
Instead of building a perfume from "ground up", many modern perfumes and colognes are made using fragrance bases or simply bases. Each base is essentially modular perfume that is blended from essential oils and aromatic chemicals, and formulated with a simple concept such as "fresh cut grass" or "juicy sour apple". Many of Guerlain's Aqua Allegoria line, with their simple fragrance concepts, are good examples of what perfume fragrance bases are like.
The effort used in developing bases by fragrance companies or individual perfumers may equal that of a marketed perfume, since they are useful in that they are reusable. On top of its reusability, the benefit in using bases for construction are quite numerous:
Ingredients with "difficult" or "overpowering" scents that are tailored into a blended base may be more easily incorporated into a work of perfume
A base may be better scent approximations of a certain thing than the extract of the thing itself. For example, a base made to embody the scent for "fresh dewy rose" might be a better approximation for the scent concept of a rose after rain than plain rose oil. Flowers whose scents cannot be extracted, such as gardenia or hyacinth, are composed as bases from data derived from headspace technology.
A perfumer can quickly rough out a concept from a brief by cobbling together multiple bases, then present it for feedback. Smoothing out the "edges" of the perfume can be done after a positive response.
Reverse engineering
Creating perfumes through reverse engineering with analytical techniques such as GC/MS can reveal the "general" formula for any particular perfume. The difficulty of GC/MS analysis arises due to the complexity of a perfume's ingredients. This is particularly due to the presence of natural essential oils and other ingredients consisting of complex chemical mixtures. However, "anyone armed with good GC/MS equipment and experienced in using this equipment can today, within days, find out a great deal about the formulation of any perfume... customers and competitors can analyze most perfumes more or less precisely."
Antique or badly preserved perfumes undergoing this analysis can also be difficult due to the numerous degradation by-products and impurities that may have resulted from breakdown of the odorous compounds. Ingredients and compounds can usually be ruled out or identified using gas chromatograph (GC) smellers, which allow individual chemical components to be identified both through their physical properties and their scent. Reverse engineering of best-selling perfumes in the market is a very common practice in the fragrance industry due to the relative simplicity of operating GC equipment, the pressure to produce marketable fragrances, and the highly lucrative nature of the perfume market.[16]
Health and environmental issues
Perfume ingredients, regardless of natural or synthetic origins, may all cause health or environmental problems when used or abused in substantial quantities. Although the areas are under active research, much remains to be learned about the effects of fragrance on human health and the environment.
Health
Immunological
Evidence in peer-reviewed journals shows that some fragrances can cause asthmatic reactions in some individuals, especially those with severe or atopic asthma. Many fragrance ingredients can also cause headaches, allergic skin reactions or nausea.
In some cases, an excessive use of perfumes may cause allergic reactions of the skin. For instance, acetophenone, ethyl acetate [citation needed] and acetone while present in many perfumes, are also known or potential respiratory allergens. Nevertheless this may be misleading, since the harm presented by many of these chemicals (either natural or synthetic) is dependent on environmental conditions and their concentrations in a perfume. For instance, linalool, which is listed as an irritant, causes skin irritation when it degrades to peroxides, however the use of antioxidants in perfumes or reduction in concentrations can prevent this. As well, the furanocoumarin present in natural extracts of grapefruit or celery can cause severe allergic reactions and increase sensitivity to ultraviolet radiation.
Some research on natural aromatics have shown that many contain compounds that cause skin irritation. However some studies, such as IFRA's research claim that opoponax is too dangerous to be used in perfumery, still lack scientific consensus. It is also true that sometimes inhalation alone can cause skin irritation.
Carcinogenicity
There is scientific evidence that nitro-musks such as Musk xylene can cause cancer while common ingredients, like certain polycyclic synthetic musks, can disrupt the balance of hormones in the human body (endocrine disruption). Some natural aromatics, such as oakmoss absolutes, contain allergens and carcinogenic compounds.
Environmental
Pollution
Synthetic musks are pleasant in smell and relatively inexpensive, as such they are often employed in large quantities to cover the unpleasant scent of laundry detergents and many personal cleaning products. Due to their large scale use, several types of synthetic musks have been found in human fat and milk, as well as in the sediments and waters of the Great Lakes.
These pollutants may pose additional health and environmental problems when they enter human and animal diets.
Species endangerment
The demands for aromatic materials like sandalwood, agarwood, musk has led to the endangerment of these species as well as illegal trafficking and harvesting.
Safety regulation
The perfume industry in the US is not directly regulated by the FDA, instead the FDA controls the safety of perfumes through their ingredients and requires that they be tested to the extent that they are Generally recognized as safe (GRAS). Due to the need for protection of trade secrets, companies rarely give the full listing of ingredients regardless of their effects on health. In Europe, as from 11 March 2005, the mandatory listing of a set of 26 recognized fragrance allergens was enforced. The requirement to list these materials is dependant on the intended use of the final product. The limits above which the allegens are required to be declared are 0.001% for products intended to remain on the skin,and 0.01% for those intended to be rinsed off. This has resulted in many old perfumes like chypres and fougère classes, which require the use of oakmoss extract, being reformulated.
Preserving perfume
Fragrance compounds in perfumes will degrade or break down if improperly stored in the presence of:
Heat
Light
Oxygen
Extraneous organic materials
Proper preservation of perfumes involve keeping them away from sources of heat and storing them where they will not be exposed to light. An opened bottle will keep its aroma intact for several years, as long as it is well stored. However the presence of oxygen in the head space of the bottle and environmental factors will in the long run alter the smell of the fragrance.
Perfumes are best preserved when kept in light-tight aluminium bottles or in their original packaging when not in use, and refrigerated to relatively low temperatures: between 3-7 degrees Celsius (37-45 degrees Fahrenheit). The Osmothèque, a perfume conservatory and museum, store their perfumes in argon evacuated aluminium flasks at 12 degrees Celsius. Although it is difficult to completely remove oxygen from the headspace of a stored flask of fragrance, opting for spray dispensers instead of rollers and "open" bottles will minimize oxygen exposure. Sprays also have the advantage of isolating fragrance inside a bottle and preventing it from mixing with dust, skin, and detritus, which would degrade and alter the quality of a perfume.
Article source : http://en.wikipedia.org/wiki/Perfume